Magnetic Behavior of Ni/NiO Core�Shell Nanoparticles under Electromagnetic Waves for Oil�Water Interfacial Tension Reduction

The increasing demand for oil and gas has led to a hope of developing more efficient recovery methods. It is well known that nanoparticles adsorbed at the oil�water interface, but there is no consensus that has been reached on whether magnetic nanoparticles under electromagnetic waves affect the interfacial tension. In this paper, nickel/nickel oxide nanoparticles have been synthesized using sol�gel auto combustion method. The product was characterized using x-ray diffraction, Raman spectroscopy, field emission scanning electron microscopy, Fourier transforms infrared spectroscopy and vibrating sample magnetometer. The results show the Ni/NiO phases and the ferromagnetic nature of the sample. The Ni/NiO nanofluids were prepared to investigate the effect on oil�water interfacial tension in enhanced oil recovery under electromagnetic waves using an inverted pendant drop method. The results show a significant decrease in interfacial tension under electromagnetic waves of frequency 2.2 kHz at low wt. of Ni/NiO and at room temperature. The decrease in the interfacial tension has been observed by increasing the temperature to 90 °C using temperature controller. The decrease in the interfacial tension could be due to the interaction of oscillating B-field of waves and magnetic domains of adsorbing nanoparticles at the oil�water interface which disturbed the oil�water interface. © 2019, ASM International.