Effect of ball milling on the catalytic conversion of cellulose to levulinic acid

Khan, A.S. and Man, Z.B. and Bustam Khalil, M.A. and Kait, C.F. and Maulud, A.S. (2014) Effect of ball milling on the catalytic conversion of cellulose to levulinic acid. Applied Mechanics and Materials, 625. pp. 353-356.

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Abstract

The yield of levulinic acid from cellulose is very low because of a strong network of intera- and intermolecular hydrogen bonding. Ball milling cause significant decrease in the cellulose crystalinity and thus increase the production of levulinic acid (LA) by using Aluminum Chloride (AlCl3) as a catalyst. By means of AlCl3 depolymerization, cellulose can produce 5- Hydroxymethylfurfural (5-HMF) and subsequently LA. The effect of reaction temperature and time were investigated. The maximum yield of LA (36.5 mol ) was achieved using 180 ͦC and 240 min. © 2014 Trans Tech Publications, Switzerland.

Item Type: Article
Impact Factor: cited By 2
Uncontrolled Keywords: Aluminum; Aluminum chloride; Cellulose; Chlorine compounds; Hydrogen bonds; Milling (machining); Organic acids, 5 hydroxymethyl furfurals; Catalytic conversion; Intermolecular hydrogen bonding; Levulinic acid; Reaction temperature, Ball milling
Depositing User: Ms Sharifah Fahimah Saiyed Yeop
Date Deposited: 29 Mar 2022 03:39
Last Modified: 29 Mar 2022 03:39
URI: http://scholars.utp.edu.my/id/eprint/31904

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